化工热力学导论（第9版）英文改编版
定价：￥128.00
作者： J M Smith，H C Van Ness等著；夏淑倩，李国柱改编
出版社：高等教育出版社
- 高等教育出版社
- 9787040627596
- 1版
- 47262424-6
- 16开
- 1060
- 工学
- 化工与制药类
- 化工与制药类
- 本科
内容简介
本书改编自J. M. Smith, H. C. Van Ness, M. M. Abbott, M. T. Swihart 著Introduction to Chemical Engineering Thermodynamics（Ninth Edition），是在保留原版教材主要知识脉络的基础上，根据我国高等学校化工类专业本科人才培养的需要进行取舍、调整、修改和编写而成的。
全书主要内容包括：热力学第一定律、热力学第二定律及它们在化工过程中的应用（含流动过程中的热力学分析、热机循环、制冷和液化）、纯流体的pVT关系、流体的热力学性质、溶液热力学框架、混合过程、相平衡、化学反应平衡、过程热力学分析等。
本书可供化学工程与工艺、环境工程、资源循环科学与工程、能源化学工程等专业本科生使用，也可供化学、化工、材料和热能工程等领域的教师、研究生和工程技术人员参考。
目录
目录
前辅文
CHAPTER 1 INTRODUCTION
1.1 The Scope of Thermodynamics
1.2 Work
1.3 Energy
1.4 Heat
1.5 Synopsis
1.6 Problems
CHAPTER 2 THE FIRST LAW AND OTHER BASIC CONCEPTS
2.1 Joule’s Experiments
2.2 Internal Energy
2.3 The First Law of Thermodynamics
2.4 Energy Balance for Closed Systems
2.5 Equilibrium and the Thermodynamic State
2.6 The Reversible Process
2.7 Closed-System Reversible Processes; Enthalpy
2.8 Heat Capacity
2.9 Mass and Energy Balances for Open Systems
2.10 Synopsis
2.11 Problems
CHAPTER 3 VOLUMETRIC PROPERTIES OF PURE FLUIDS
3.1 PVT Behavior of Pure Substances
3.2 Virial Equations of State
3.3 Application of the Virial Equations
3.4 Cubic Equations of State
3.5 Generalized Correlations for Gases
3.6 Generalized Correlations for Liquids
3.7 Synopsis
3.8 Problems
CHAPTER 4 THE SECOND LAW OF THERMODYNAMICS
4.1 Axiomatic Statements of the Second Law
4.2 Heat Engines and Heat Pumps
4.3 Entropy
4.4 Entropy Changes for the Ideal-Gas State
4.5 Entropy Balance for Open Systems
4.6 Calculation of Ideal Work
4.7 Lost Work
4.8 The Third Law of Thermodynamics
4.9 Entropy from the Microscopic Viewpoint
4.10 Synopsis
4.11 Problems
CHAPTER 5 THERMODYNAMIC PROPERTIES OF FLUIDS
5.1 Fundamental Property Relations
5.2 Residual Properties
5.3 Residual Properties from the Virial Equations of State
5.4 Generalized Property Correlations for Gases
5.5 Two-Phase Systems
5.6 Thermodynamic Diagrams
5.7 Tables of Thermodynamic Properties
5.8 Synopsis
5.9 Addendum. Residual Properties in the Zero-Pressure Limit
5.10 Problems
CHAPTER 6 APPLICATIONS OF THERMODYNAMICS TO FLOW PROCESSES
6.1 Duct Flow of Compressible Fluids
6.2 Turbines (Expanders)
6.3 Compression Processes
6.4 Synopsis
6.5 Problems
CHAPTER 7 PRODUCTION OF POWER FROM HEAT
7.1 The Steam Power Plant
7.2 Internal-Combustion Engines
7.3 Jet Engines; Rocket Engines
7.4 Synopsis
7.5 Problems
CHAPTER 8 REFRIGERATION AND LIQUEFACTION
8.1 The Carnot Refrigerator
8.2 The Vapor-Compression Cycle
8.3 The Choice of Refrigerant
8.4 Absorption Refrigeration
8.5 The Heat Pump
8.6 Liquefaction Processes
8.7 Synopsis
8.8 Problems
CHAPTER 9 THE FRAMEWORK OF SOLUTION THERMODYNAMICS
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Equilibrium
9.3 Partial Properties
9.4 The Ideal-Gas-State Mixture Model
9.5 Fugacity and Fugacity Coefficient: Pure Species
9.6 Fugacity and Fugacity Coefficient: Species in Solution
9.7 Generalized Correlations for the Fugacity Coefficient
9.8 The Ideal-Solution Model
9.9 Excess Properties
9.10 Synopsis
9.11 Problems
CHAPTER 10 MIXING PROCESSES
10.1 Property Changes of Mixing
10.2 Heat Effects of Mixing Processes
10.3 Synopsis
10.4 Problems
CHAPTER 11 PHASE EQUILIBRIUM: INTRODUCTION
11.1 The Nature of Equilibrium
11.2 Vapor/Liquid Equilibrium: Qualitative Behavior
11.3 Equilibrium and Phase Stability
11.4 Vapor/Liquid/Liquid Equilibrium
11.5 Synopsis
11.6 Problems
CHAPTER 12 THERMODYNAMIC FORMULATIONS FOR VAPOR/LIQUID EQUILIBRIUM
12.1 Excess Gibbs Energy and Activity Coefficients
12.2 The Gamma/Phi Formulation of VLE
12.3 Correlations for Liquid-Phase Activity Coefficients
12.4 Fitting Activity Coefficient Models to VLE Data
12.5 Residual Properties by Cubic Equations of State
12.6 VLE from Cubic Equations of State
12.7 Flash Calculations
12.8 Synopsis
12.9 Problems
CHAPTER 13 CHEMICAL-REACTION EQUILIBRIA
13.1 The Reaction Coordinate
13.2 Application of Equilibrium Criteria to Chemical Reactions
13.3 The Standard Gibbs-Energy Change and the Equilibrium Constant
13.4 Effect of Temperature on the Equilibrium Constant
13.5 Evaluation of Equilibrium Constants
13.6 Relation of Equilibrium Constants to Composition
13.7 Equilibrium Conversions for Single Reactions
13.8 Multireaction Equilibria
13.9 Fuel Cells
13.10 Synopsis
13.11 Problems
CHAPTER 14 TOPICS IN PHASE EQUILIBRIA
14.1 Liquid/Liquid Equilibrium
14.2 Vapor/Liquid/Liquid Equilibrium (VLLE)
14.3 Solid/Liquid Equilibrium (SLE)
14.4 Solid/Vapor Equilibrium (SVE)
14.5 Osmotic Equilibrium and Osmotic Pressure
14.6 Synopsis
14.7 Problems
CHAPTER 15 THERMODYNAMIC ANALYSIS OF PROCESSES
15.1 Thermodynamic Analysis of Steady-State Flow Processes
15.2 Synopsis
15.3 Problems
APPENDIX A PROPERTIES OF PURE SPECIES
APPENDIX B HEAT CAPACITIES AND PROPERTY CHANGES OF FORMATION
APPENDIX C THERMODYNAMIC DIAGRAMS
前辅文
CHAPTER 1 INTRODUCTION
1.1 The Scope of Thermodynamics
1.2 Work
1.3 Energy
1.4 Heat
1.5 Synopsis
1.6 Problems
CHAPTER 2 THE FIRST LAW AND OTHER BASIC CONCEPTS
2.1 Joule’s Experiments
2.2 Internal Energy
2.3 The First Law of Thermodynamics
2.4 Energy Balance for Closed Systems
2.5 Equilibrium and the Thermodynamic State
2.6 The Reversible Process
2.7 Closed-System Reversible Processes; Enthalpy
2.8 Heat Capacity
2.9 Mass and Energy Balances for Open Systems
2.10 Synopsis
2.11 Problems
CHAPTER 3 VOLUMETRIC PROPERTIES OF PURE FLUIDS
3.1 PVT Behavior of Pure Substances
3.2 Virial Equations of State
3.3 Application of the Virial Equations
3.4 Cubic Equations of State
3.5 Generalized Correlations for Gases
3.6 Generalized Correlations for Liquids
3.7 Synopsis
3.8 Problems
CHAPTER 4 THE SECOND LAW OF THERMODYNAMICS
4.1 Axiomatic Statements of the Second Law
4.2 Heat Engines and Heat Pumps
4.3 Entropy
4.4 Entropy Changes for the Ideal-Gas State
4.5 Entropy Balance for Open Systems
4.6 Calculation of Ideal Work
4.7 Lost Work
4.8 The Third Law of Thermodynamics
4.9 Entropy from the Microscopic Viewpoint
4.10 Synopsis
4.11 Problems
CHAPTER 5 THERMODYNAMIC PROPERTIES OF FLUIDS
5.1 Fundamental Property Relations
5.2 Residual Properties
5.3 Residual Properties from the Virial Equations of State
5.4 Generalized Property Correlations for Gases
5.5 Two-Phase Systems
5.6 Thermodynamic Diagrams
5.7 Tables of Thermodynamic Properties
5.8 Synopsis
5.9 Addendum. Residual Properties in the Zero-Pressure Limit
5.10 Problems
CHAPTER 6 APPLICATIONS OF THERMODYNAMICS TO FLOW PROCESSES
6.1 Duct Flow of Compressible Fluids
6.2 Turbines (Expanders)
6.3 Compression Processes
6.4 Synopsis
6.5 Problems
CHAPTER 7 PRODUCTION OF POWER FROM HEAT
7.1 The Steam Power Plant
7.2 Internal-Combustion Engines
7.3 Jet Engines; Rocket Engines
7.4 Synopsis
7.5 Problems
CHAPTER 8 REFRIGERATION AND LIQUEFACTION
8.1 The Carnot Refrigerator
8.2 The Vapor-Compression Cycle
8.3 The Choice of Refrigerant
8.4 Absorption Refrigeration
8.5 The Heat Pump
8.6 Liquefaction Processes
8.7 Synopsis
8.8 Problems
CHAPTER 9 THE FRAMEWORK OF SOLUTION THERMODYNAMICS
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Equilibrium
9.3 Partial Properties
9.4 The Ideal-Gas-State Mixture Model
9.5 Fugacity and Fugacity Coefficient: Pure Species
9.6 Fugacity and Fugacity Coefficient: Species in Solution
9.7 Generalized Correlations for the Fugacity Coefficient
9.8 The Ideal-Solution Model
9.9 Excess Properties
9.10 Synopsis
9.11 Problems
CHAPTER 10 MIXING PROCESSES
10.1 Property Changes of Mixing
10.2 Heat Effects of Mixing Processes
10.3 Synopsis
10.4 Problems
CHAPTER 11 PHASE EQUILIBRIUM: INTRODUCTION
11.1 The Nature of Equilibrium
11.2 Vapor/Liquid Equilibrium: Qualitative Behavior
11.3 Equilibrium and Phase Stability
11.4 Vapor/Liquid/Liquid Equilibrium
11.5 Synopsis
11.6 Problems
CHAPTER 12 THERMODYNAMIC FORMULATIONS FOR VAPOR/LIQUID EQUILIBRIUM
12.1 Excess Gibbs Energy and Activity Coefficients
12.2 The Gamma/Phi Formulation of VLE
12.3 Correlations for Liquid-Phase Activity Coefficients
12.4 Fitting Activity Coefficient Models to VLE Data
12.5 Residual Properties by Cubic Equations of State
12.6 VLE from Cubic Equations of State
12.7 Flash Calculations
12.8 Synopsis
12.9 Problems
CHAPTER 13 CHEMICAL-REACTION EQUILIBRIA
13.1 The Reaction Coordinate
13.2 Application of Equilibrium Criteria to Chemical Reactions
13.3 The Standard Gibbs-Energy Change and the Equilibrium Constant
13.4 Effect of Temperature on the Equilibrium Constant
13.5 Evaluation of Equilibrium Constants
13.6 Relation of Equilibrium Constants to Composition
13.7 Equilibrium Conversions for Single Reactions
13.8 Multireaction Equilibria
13.9 Fuel Cells
13.10 Synopsis
13.11 Problems
CHAPTER 14 TOPICS IN PHASE EQUILIBRIA
14.1 Liquid/Liquid Equilibrium
14.2 Vapor/Liquid/Liquid Equilibrium (VLLE)
14.3 Solid/Liquid Equilibrium (SLE)
14.4 Solid/Vapor Equilibrium (SVE)
14.5 Osmotic Equilibrium and Osmotic Pressure
14.6 Synopsis
14.7 Problems
CHAPTER 15 THERMODYNAMIC ANALYSIS OF PROCESSES
15.1 Thermodynamic Analysis of Steady-State Flow Processes
15.2 Synopsis
15.3 Problems
APPENDIX A PROPERTIES OF PURE SPECIES
APPENDIX B HEAT CAPACITIES AND PROPERTY CHANGES OF FORMATION
APPENDIX C THERMODYNAMIC DIAGRAMS
前辅文
CHAPTER 1 INTRODUCTION
1.1 The Scope of Thermodynamics
1.2 Work
1.3 Energy
1.4 Heat
1.5 Synopsis
1.6 Problems
CHAPTER 2 THE FIRST LAW AND OTHER BASIC CONCEPTS
2.1 Joule’s Experiments
2.2 Internal Energy
2.3 The First Law of Thermodynamics
2.4 Energy Balance for Closed Systems
2.5 Equilibrium and the Thermodynamic State
2.6 The Reversible Process
2.7 Closed-System Reversible Processes; Enthalpy
2.8 Heat Capacity
2.9 Mass and Energy Balances for Open Systems
2.10 Synopsis
2.11 Problems
CHAPTER 3 VOLUMETRIC PROPERTIES OF PURE FLUIDS
3.1 PVT Behavior of Pure Substances
3.2 Virial Equations of State
3.3 Application of the Virial Equations
3.4 Cubic Equations of State
3.5 Generalized Correlations for Gases
3.6 Generalized Correlations for Liquids
3.7 Synopsis
3.8 Problems
CHAPTER 4 THE SECOND LAW OF THERMODYNAMICS
4.1 Axiomatic Statements of the Second Law
4.2 Heat Engines and Heat Pumps
4.3 Entropy
4.4 Entropy Changes for the Ideal-Gas State
4.5 Entropy Balance for Open Systems
4.6 Calculation of Ideal Work
4.7 Lost Work
4.8 The Third Law of Thermodynamics
4.9 Entropy from the Microscopic Viewpoint
4.10 Synopsis
4.11 Problems
CHAPTER 5 THERMODYNAMIC PROPERTIES OF FLUIDS
5.1 Fundamental Property Relations
5.2 Residual Properties
5.3 Residual Properties from the Virial Equations of State
5.4 Generalized Property Correlations for Gases
5.5 Two-Phase Systems
5.6 Thermodynamic Diagrams
5.7 Tables of Thermodynamic Properties
5.8 Synopsis
5.9 Addendum. Residual Properties in the Zero-Pressure Limit
5.10 Problems
CHAPTER 6 APPLICATIONS OF THERMODYNAMICS TO FLOW PROCESSES
6.1 Duct Flow of Compressible Fluids
6.2 Turbines (Expanders)
6.3 Compression Processes
6.4 Synopsis
6.5 Problems
CHAPTER 7 PRODUCTION OF POWER FROM HEAT
7.1 The Steam Power Plant
7.2 Internal-Combustion Engines
7.3 Jet Engines; Rocket Engines
7.4 Synopsis
7.5 Problems
CHAPTER 8 REFRIGERATION AND LIQUEFACTION
8.1 The Carnot Refrigerator
8.2 The Vapor-Compression Cycle
8.3 The Choice of Refrigerant
8.4 Absorption Refrigeration
8.5 The Heat Pump
8.6 Liquefaction Processes
8.7 Synopsis
8.8 Problems
CHAPTER 9 THE FRAMEWORK OF SOLUTION THERMODYNAMICS
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Equilibrium
9.3 Partial Properties
9.4 The Ideal-Gas-State Mixture Model
9.5 Fugacity and Fugacity Coefficient: Pure Species
9.6 Fugacity and Fugacity Coefficient: Species in Solution
9.7 Generalized Correlations for the Fugacity Coefficient
9.8 The Ideal-Solution Model
9.9 Excess Properties
9.10 Synopsis
9.11 Problems
CHAPTER 10 MIXING PROCESSES
10.1 Property Changes of Mixing
10.2 Heat Effects of Mixing Processes
10.3 Synopsis
10.4 Problems
CHAPTER 11 PHASE EQUILIBRIUM: INTRODUCTION
11.1 The Nature of Equilibrium
11.2 Vapor/Liquid Equilibrium: Qualitative Behavior
11.3 Equilibrium and Phase Stability
11.4 Vapor/Liquid/Liquid Equilibrium
11.5 Synopsis
11.6 Problems
CHAPTER 12 THERMODYNAMIC FORMULATIONS FOR VAPOR/LIQUID EQUILIBRIUM
12.1 Excess Gibbs Energy and Activity Coefficients
12.2 The Gamma/Phi Formulation of VLE
12.3 Correlations for Liquid-Phase Activity Coefficients
12.4 Fitting Activity Coefficient Models to VLE Data
12.5 Residual Properties by Cubic Equations of State
12.6 VLE from Cubic Equations of State
12.7 Flash Calculations
12.8 Synopsis
12.9 Problems
CHAPTER 13 CHEMICAL-REACTION EQUILIBRIA
13.1 The Reaction Coordinate
13.2 Application of Equilibrium Criteria to Chemical Reactions
13.3 The Standard Gibbs-Energy Change and the Equilibrium Constant
13.4 Effect of Temperature on the Equilibrium Constant
13.5 Evaluation of Equilibrium Constants
13.6 Relation of Equilibrium Constants to Composition
13.7 Equilibrium Conversions for Single Reactions
13.8 Multireaction Equilibria
13.9 Fuel Cells
13.10 Synopsis
13.11 Problems
CHAPTER 14 TOPICS IN PHASE EQUILIBRIA
14.1 Liquid/Liquid Equilibrium
14.2 Vapor/Liquid/Liquid Equilibrium (VLLE)
14.3 Solid/Liquid Equilibrium (SLE)
14.4 Solid/Vapor Equilibrium (SVE)
14.5 Osmotic Equilibrium and Osmotic Pressure
14.6 Synopsis
14.7 Problems
CHAPTER 15 THERMODYNAMIC ANALYSIS OF PROCESSES
15.1 Thermodynamic Analysis of Steady-State Flow Processes
15.2 Synopsis
15.3 Problems
APPENDIX A PROPERTIES OF PURE SPECIES
APPENDIX B HEAT CAPACITIES AND PROPERTY CHANGES OF FORMATION
APPENDIX C THERMODYNAMIC DIAGRAMS
前辅文
CHAPTER 1 INTRODUCTION
1.1 The Scope of Thermodynamics
1.2 Work
1.3 Energy
1.4 Heat
1.5 Synopsis
1.6 Problems
CHAPTER 2 THE FIRST LAW AND OTHER BASIC CONCEPTS
2.1 Joule’s Experiments
2.2 Internal Energy
2.3 The First Law of Thermodynamics
2.4 Energy Balance for Closed Systems
2.5 Equilibrium and the Thermodynamic State
2.6 The Reversible Process
2.7 Closed-System Reversible Processes; Enthalpy
2.8 Heat Capacity
2.9 Mass and Energy Balances for Open Systems
2.10 Synopsis
2.11 Problems
CHAPTER 3 VOLUMETRIC PROPERTIES OF PURE FLUIDS
3.1 PVT Behavior of Pure Substances
3.2 Virial Equations of State
3.3 Application of the Virial Equations
3.4 Cubic Equations of State
3.5 Generalized Correlations for Gases
3.6 Generalized Correlations for Liquids
3.7 Synopsis
3.8 Problems
CHAPTER 4 THE SECOND LAW OF THERMODYNAMICS
4.1 Axiomatic Statements of the Second Law
4.2 Heat Engines and Heat Pumps
4.3 Entropy
4.4 Entropy Changes for the Ideal-Gas State
4.5 Entropy Balance for Open Systems
4.6 Calculation of Ideal Work
4.7 Lost Work
4.8 The Third Law of Thermodynamics
4.9 Entropy from the Microscopic Viewpoint
4.10 Synopsis
4.11 Problems
CHAPTER 5 THERMODYNAMIC PROPERTIES OF FLUIDS
5.1 Fundamental Property Relations
5.2 Residual Properties
5.3 Residual Properties from the Virial Equations of State
5.4 Generalized Property Correlations for Gases
5.5 Two-Phase Systems
5.6 Thermodynamic Diagrams
5.7 Tables of Thermodynamic Properties
5.8 Synopsis
5.9 Addendum. Residual Properties in the Zero-Pressure Limit
5.10 Problems
CHAPTER 6 APPLICATIONS OF THERMODYNAMICS TO FLOW PROCESSES
6.1 Duct Flow of Compressible Fluids
6.2 Turbines (Expanders)
6.3 Compression Processes
6.4 Synopsis
6.5 Problems
CHAPTER 7 PRODUCTION OF POWER FROM HEAT
7.1 The Steam Power Plant
7.2 Internal-Combustion Engines
7.3 Jet Engines; Rocket Engines
7.4 Synopsis
7.5 Problems
CHAPTER 8 REFRIGERATION AND LIQUEFACTION
8.1 The Carnot Refrigerator
8.2 The Vapor-Compression Cycle
8.3 The Choice of Refrigerant
8.4 Absorption Refrigeration
8.5 The Heat Pump
8.6 Liquefaction Processes
8.7 Synopsis
8.8 Problems
CHAPTER 9 THE FRAMEWORK OF SOLUTION THERMODYNAMICS
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Equilibrium
9.3 Partial Properties
9.4 The Ideal-Gas-State Mixture Model
9.5 Fugacity and Fugacity Coefficient: Pure Species
9.6 Fugacity and Fugacity Coefficient: Species in Solution
9.7 Generalized Correlations for the Fugacity Coefficient
9.8 The Ideal-Solution Model
9.9 Excess Properties
9.10 Synopsis
9.11 Problems
CHAPTER 10 MIXING PROCESSES
10.1 Property Changes of Mixing
10.2 Heat Effects of Mixing Processes
10.3 Synopsis
10.4 Problems
CHAPTER 11 PHASE EQUILIBRIUM: INTRODUCTION
11.1 The Nature of Equilibrium
11.2 Vapor/Liquid Equilibrium: Qualitative Behavior
11.3 Equilibrium and Phase Stability
11.4 Vapor/Liquid/Liquid Equilibrium
11.5 Synopsis
11.6 Problems
CHAPTER 12 THERMODYNAMIC FORMULATIONS FOR VAPOR/LIQUID EQUILIBRIUM
12.1 Excess Gibbs Energy and Activity Coefficients
12.2 The Gamma/Phi Formulation of VLE
12.3 Correlations for Liquid-Phase Activity Coefficients
12.4 Fitting Activity Coefficient Models to VLE Data
12.5 Residual Properties by Cubic Equations of State
12.6 VLE from Cubic Equations of State
12.7 Flash Calculations
12.8 Synopsis
12.9 Problems
CHAPTER 13 CHEMICAL-REACTION EQUILIBRIA
13.1 The Reaction Coordinate
13.2 Application of Equilibrium Criteria to Chemical Reactions
13.3 The Standard Gibbs-Energy Change and the Equilibrium Constant
13.4 Effect of Temperature on the Equilibrium Constant
13.5 Evaluation of Equilibrium Constants
13.6 Relation of Equilibrium Constants to Composition
13.7 Equilibrium Conversions for Single Reactions
13.8 Multireaction Equilibria
13.9 Fuel Cells
13.10 Synopsis
13.11 Problems
CHAPTER 14 TOPICS IN PHASE EQUILIBRIA
14.1 Liquid/Liquid Equilibrium
14.2 Vapor/Liquid/Liquid Equilibrium (VLLE)
14.3 Solid/Liquid Equilibrium (SLE)
14.4 Solid/Vapor Equilibrium (SVE)
14.5 Osmotic Equilibrium and Osmotic Pressure
14.6 Synopsis
14.7 Problems
CHAPTER 15 THERMODYNAMIC ANALYSIS OF PROCESSES
15.1 Thermodynamic Analysis of Steady-State Flow Processes
15.2 Synopsis
15.3 Problems
APPENDIX A PROPERTIES OF PURE SPECIES
APPENDIX B HEAT CAPACITIES AND PROPERTY CHANGES OF FORMATION
APPENDIX C THERMODYNAMIC DIAGRAMS
