ⅠInorganic Chemistry1
Chapter 1Introduction2
11Observations and Conclusions3
12The Scientific Method3
13Units of Measurement5
14Advice on Studying Chemistry8
Key Words8
Chapter 2Structures of Atoms9
21Particles in Atoms10
22The Bohr Model12
23The Wave Theory of Electrons13
24Heisenbergs Uncertainty Principle14
25The Schrdinger Equation14
26Quantum Numbers15
27Shapes of Atomic Orbitals17
28ManyElectron Atoms19
29Valence Electrons24
210The Periodic Table and Electronic Configurations of Atoms24
211The Periodicity of the Properties of Elements and Atomic Structure26
Key Words30
Exercises31
Chapter 3Chemical bonds33
31Ionic Bonds33
32Covalent Bonds35
33Lewis Dot Symbols and Lewis Structure37
34Sigma and Pi Bonds43
35Bond Polarity44
36Bond Energy, Bond Length and Bond Angle45
37Molecular Geometry47
38The VSEPR Model47
39Hybrid Orbitals51
310Molecular Orbitals56
311Intermolecular Force64
Key Words71
Exercises71
Chapter 4Thermochemistry74
41First Law of Thermodynamics74
42Enthalpy and Enthalpy Change75
43Hesss Law76
44Entropy and the Second Law of Thermodynamics 79
45Spontaneous Processes and Gibbs Free Energy80
46Temperature and Direction of Spontaneous Change81
47Standard Free Energy of Formation and Standard Free Energy of Reaction82
Key Words83
Exercises83
Chapter 5Chemical Kinetics85
51Reaction Rates85
52Theories of Reaction Rates 87
53Effect of Concentration on Rate of Reaction89
54Rate and Temperature92
55Catalysis94
Key Words95
Exercises96
Chapter 6Chemical Equilibrium98
61Concept of Equilibrium98
62Equilibrium Constant98
63Le Chteliers Principle103
Key Words106
Exercises106
Chapter 7Solutions108
71Ways of Expressing Concentration108
72Colligative Properties113
Key Words124
Exercises125
Chapter 8Solubility Equilibrium127
81Saturated Solutions and Solubility127
82Solubility Equilibria127
83Factors Affecting Solubility130
84Predicting Precipitation Reaction132
85Selective Precipitation134
86Application of Precipitate on Medicine137
Key Words138
Exercises139
Chapter 9AcidBase Equilibria141
91Acids and Bases141
92Ion Product of Water143
93Strength of Weak Acids and Bases144
94The pH of Weak Acids and Bases146
95The CommonIon Effect148
96Buffer Solutions150
Key Words153
Exercises153
Chapter 10An Introduction to Electrochemistry155
101OxidationReduction Reactions155
102Balancing OxidationReduction Equations158
103Voltaic Cells161
104Standard Cell Electromotive Force164
105Electrochemistry and Thermodynamics171
106Effect of Concentration on Cell EMF172
107Reduction Potential Diagrams of Elements(Latimer Diagrams)174
Key Words177
Exercises177
Chapter 11Chemistry of Coordination Compounds180
111The History of Coordination Chemistry180
112Formation of Coordination Compound182
113Nomenclature of Coordination Compounds184
114Structure and Isomerism 185
115Coordination Equilibrium in Solution187
116Valence Bond Theory of Coordination Compounds191
117The Crystal Field Theory194
118The Biological Effects of Coordination Compounds199
Key Words200
Exercises201
Chapter 12Nonmetals and Semimetals203
121General Concepts203
122Hydrogen203
123Boron204
124The Group ⅣA Elements，the Carbon Group Elements205
125The GroupⅤA Elements，the Nitrogen Group Elements208
126The Group ⅥA Elements，the Oxygen Group Elements211
127The Group ⅦA Elements，the Halogens215
128The Group ⅧA Elements，the Noble Gases218
Key Words218
Exercises219
Chapter 13Metals 220
131The Group IA Elements220
132The Group ⅡA Elements224
133The Group ⅢA Elements229
134A Survey of Transition Metals232
135Chemistry of Some Transition Metals234
Key Words239
Exercises239
ⅡInorganic Chemical Experiments241
Chapter 1Basic Techniques of Experimental Chemistry242
11Safety242
12Recording Results243
13Weighing243
14Concerning Liquids244
Chapter 2Typical Chemical Laboratory Apparatus 252
Chapter 3Experiments254
31Some Elementary Operation254
32AcidBase Titration256
33Electrolyte Solutions259
34Preparation of Officinal Sodium Chloride and Its Purity Examination 262
35OxidationReduction Reactions267
36Coordination Compounds271
37The Halogens275
38Chromium,Manganese and Iron278
39Copper,Silver,Zinc and Mercury283
310Determination of the Ionization Constant of HAc by pH Meter287
311Preparation of Ammonium Iron(Ⅱ)Sulfate291
312Preparation and Content Determination of Zinc Gluconate294
Appendix296
Reference308